Mica as a filler

History

Historically, crystal of Mica has been used as a transparent plate until glass was discovered. It was also being used as an electrical insulation for a long time.

In the 1960s and the 1970s, Dr. Raymond T. Woodhams from University of Toronto played a central role for the research of Mica. He focused on the high aspect ratio of Mica and discovered its high rigidity which can be applied for plastics. This discovery drew attention on the possibility to use Mica as a sheet reinforcing material and expanded its applied field.

Features

Mica, which is used in various fields as a filler, has a number of advantages the same as other inorganic fillers as listed below.

FunctionsInorganic Filler
MechanicalStrengthMica, Glass Fibre, Carbon Fibre, Talc
Dimensional StabilityMica, Alumina, Silica, Clay, Talc
ElectricalInsulationMica, Clay, Talc, Silica
ThermalHeat ResistanceMica, Silica, Talc, Glass Fibre, Carbon Fibre
Sound/VibrationMica, Iron, Lead, Iron Oxide
ChemicalFlame ResistingMica, Aluminum Hydroxide, Antimony Trioxide, Hydrous Sillicate
Chemical ResistanceMica, Alumina, Silica, Clay, Talc
Water ResistanceMica, Silica, Clay, Talc

The difference of physical properties of Mica and other inorganic fillers compounded with PBT is illustrated in the following table.

Inorganic FillerMicaTalcWollas-toniteGlass BeadsMilled FibreGlass Fibre
Tensile Strength(MPa)557658605660120
Tensile Elongation (%)>200323543
Bending Strength (MPa)9213099106105116190
Flexural Modulus (GPa)2.58.26.04.54.04.48.2
Impact Strength
(Izod)(J/m)
45302830333282
Heat Distortion Temperature (℃)5516215010085120205
Mold Shrinkage (MD)(%)1.70.71.11.51.51.30.2
Mold Shrinkage (TD)(%)1.80.81.51.71.61.21.3
*Combined ratio is 30wt%
*”プラスチック活用ノート 材料選択のための基礎資料集 四訂版” pg.272. Oi, Hidesaburo and Hirota, Yutaka.